I didn't have time to take screenshots, but it appeared that the BACC boosters were "overlapping" the central booster physically. I put some Modular Girder Segments in the same radial patter, and put the decouplers on those, then attached the BACCs to the decouplers in the same fashion. (I have had trouble in the past with alignment, so I knew it wasn't a matter of "missing the decouplers". I was super careful, and put a lot of slow effort into making sure the staging and alignment of the decouplers was right. It turns out the Girders put enough distance between the BACCs and the main booster that the decouplers worked. I got a big Career mode boost from testing the S1 SRB-KD25k at altitude. Thanks for the suggestions!