Once you get within a couple kilometers, set the Navball to "Target" mode (and make sure you have the other ship set as your target.) It will show your relative speed to the target vessel. You can zero your speed by burning on the retrograde marker. Then, aim toward the pro-target marker and burn, trying to keep your prograde on that marker. Once you get close, slow down and make sure to control from the docking port by right-clicking it and selecting "control from here". It also helps to make sure the other ship's docking port is facing towards you so you don't have to deal with trying to circle around it. I hope this helps