Silicon occupies the same column as carbon on the periodic table and can form many similar molecules, which is why it seems so promising and is so popular in sci-fi, but it's not a perfect analog to carbon. Take silicon dioxide for instance, the silicon analog to the waste gas carbon dioxide. Also known as silica, silicon dioxide is a solid at room temperature and is what makes up quartz and glass. It's basically a rock. CO2 is also soluble in water whereas SO2 doesn't dissolve at all. That, combined with the fact that silicon is like 10 times more common on Earth than carbon, yet life evolved to use carbon anyway, makes silicon-based life seem unlikely. That's not to say that it is outright impossible -- silicon might behave differently at much higher temperatures and with a solvent more alkaline than water, but we really don't know enough to say for sure whether it really could support life or not, or if there would be easier alternatives for life to use. Trust me, it's not arrogance or close-mindedness or anything of the sort. Any scientist in any field would be thrilled beyond words at the discovery of alien life with an alien biochemistry. The problem is that we only have one example of how life looks, one example we know works, and we wouldn't even know where to begin looking for anything else. Alternative biochemistries have been proposed, but most of them fall short in one way or another, so we aren't sure anything else can exist. It's much more productive to look for something of which we already have proof of concept than to reach out in the dark when we aren't even sure anything's out there.